Ethyl 2-acetylhydrazono-2-phenylacetate
نویسندگان
چکیده
The title compound, C(12)H(14)N(2)O(3), was synthesized as an inter-mediate for the synthesis of metamitron. The benzene ring forms dihedral angles of 86.3 (2) and 10.0 (3)° with the ethyl group and the acetyl-imino plane, respectively. The crystal structure involves inter-molecular C-H⋯O and N-H⋯O hydrogen bonds.
منابع مشابه
Guanidinium 2-phenylacetate
In the structure of the title salt, CH(6)N(3) (+)·C(8)H(7)O(2) (-), the guanidinium cation gives three cyclic hydrogen-bonding inter-actions with O-atom acceptors of three independent phenyl-acetate anions, one R(2) (2)(8) and two R(2) (1)(6), giving one-dimensional columnar structures which extend down the 4(2) axis in the tetra-gonal cell. Within these structures, there are solvent-accessible...
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The title compound, C(10)H(12)N(4)O(2), was prepared as an inter-mediate for the synthesis of metamitron. The benzene ring plane forms dihedral angles of 66.0 (1) and 3.5 (5)° with the hydrazine plane and the acetyl-imino plane, respectively. The crystal structure involves inter-molecular N-H⋯O hydrogen bonds.
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In the title compound, [Cu(C(8)H(7)O(2))(C(12)H(8)N(2))(2)](C(8)H(7)O(2))·6H(2)O, the Cu atom is in a distorted square-pyramidal coordination environment. The six crystallographically independent uncoordinated water mol-ecules are inter-connected by hydrogen bonds, completing dodeca-water (H(2)O)(12) clusters which are hydrogen bonded to the carboxyl-ate groups of phenyl-acetate anions, buildin...
متن کامل4-Carbamoylpiperidinium phenylacetate hemihydrate
The asymmetric unit of the title compound, C(6)H(13)N(2)O(+)·C(8)H(7)O(2) (-)·0.5H(2)O, comprises two isonipecotamide cations, two phenyl-acetate anions and a water mol-ecule of solvation. The hydrogen-bonding environments for both sets of ion pairs are essentially identical with the piperidinium and amide 'ends' of each cation involved in lateral heteromolecular hydrogen-bonded cyclic N-H⋯O as...
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In the title compound, [Cd(C(9)H(10)NS(2))(2)(C(5)H(9)NO)], the Cd(II) atom is five-coordinated in a distorted square-pyramidal geometry by four S atoms from two chelating N-ethyl-N-phenyl dithio-carbamate ligands and one N atom from a 2-ethyl-2-oxazoline ligand. Inter-molecular C-H⋯π inter-actions are observed in the crystal structure.
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